It's really just a fancy way with how your company's balance sheets change during the day and do not normally require the intervention of negotiations with your regular finance providers. The internet provides a lot of definitions for this, but you would basically need to understand that spontaneous financing just means that when the values in your accounts change, so does the amount of assets / cash the company requires in order to have the whole sheet balanced.
Trade credit , and other payables and accruals that arise spontaneously in the entity`s day-to-day operations.